Effects of La Concentration on the Structural and Dielectric Properties of 0.57BiFeO3-0.43PbTiO3 Crystalline Solutions

Jianguo Chen, Jinrong Cheng, Shengwen Yu, Dengren Jin, and Zhongyan Meng

ABSTRACT Crystalline solutions of 0.57(Bi1-xLax)FeO3-0.43PbTiO3 (BLF-PT) for x = 0, 0.1, 0.2, and 0.3 were fabricated by the traditional solid state reaction method. X-ray diffraction analysis revealed that the tetragonal-to-rhombohedral phase transformation of BLF-PT occurred with an increase of the La content. The dielectric and ferroelectric properties of BLF-PT were investigated at room temperature for different La contents. BLF-PT revealed strong ferroelectric characteristics for the lower La composition, and transferred to relaxor ferroelectrics for x > 0.2. The dielectric constant and remanent polarization were 1461 and 33.5 μC/cm2, respectively, for BLF-PT of x = 0.2. The dielectric constant and polarization of BLF-PT were enhanced simultaneously with increasing La content. Our results demonstrate that BLF-PT is a competitive piezoelectric ceramic.

Digital Object Identifier 10.1109/TUFFC.2007.591

© 2007, by The Institute of Electrical and Electronics Engineers, Inc. All rights reserved.

Back to Table of Contents